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There are many equations that describe the thermodynamic state and properties of steam. While some of these equations are accurate in generating property tables, they are not suitable for fast CFD computations. Therefore, ANSYS FLUENT uses a simpler form of the thermodynamic state equations [ 386] for efficient CFD calculations that are accurate over a wide range of temperatures and pressures. These equations are described below.
Equation of State
The steam equation of state used in the solver, which relates the pressure to the vapor density and the temperature, is given by [ 386]:
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(16.6-13) |
where
, and
are the second and the third virial coefficients given by the following empirical functions:
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(16.6-14) |
where
is given in
/kg,
=
with
given in Kelvin,
= 10000.0,
= 0.0015,
= -0.000942, and
= -0.0004882.
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(16.6-15) |
where
is given in
/
,
=
with
given in Kelvin,
= 0.8978,
=11.16,
= 1.772, and
= 1.5E-06.
The two empirical functions that define the virial coefficients
and
cover the temperature range from 273 K to 1073 K.
The vapor isobaric specific heat capacity
is given by:
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(16.6-16) |
The vapor specific enthalpy,
is given by:
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(16.6-17) |
The vapor specific entropy,
is given by:
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(16.6-18) |
The isobaric specific heat at zero pressure is defined by the following empirical equation:
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(16.6-19) |
where
is in KJ/kg K,
= 46.0,
= 1.47276,
= 8.38930E-04,
= -2.19989E-07,
= 2.46619E-10, and
= -9.70466E-14.
and
=
,
=
,
=
, and
=
.
Both
and
are functions of temperature and they are defined by:
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(16.6-20) |
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(16.6-21) |
where
and
are arbitrary constants.
The vapor dynamic viscosity
and thermal conductivity
are also functions of temperature and were obtained from [
385].
Saturated Vapor Line
The saturation pressure equation as a function of temperature was obtained from [ 290]. The example provided in this section in the separate User's Guide contains a function called wetst_satP() that represents the formulation for the saturation pressure.
Saturated Liquid Line
At the saturated liquid-line, the liquid density, surface tension, specific heat
, dynamic viscosity, and thermal conductivity must be defined. The equation for liquid density,
, was obtained from [
290]. The liquid surface tension equation was obtained from [
385]. While the values of
,
and
were curve fit using published data from [
83] and then written in polynomial forms. The example provided in
this section in the separate
User's Guide contains functions called
wetst_cpl(),
wetst_mul(), and
wetst_ktl() that represent formulations for
,
and
.
Mixture Properties
The mixture properties are related to vapor and liquid properties via the wetness factor using the following mixing law:
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(16.6-22) |
where
represents any of the following thermodynamic properties:
,
,
,
,
or
.